Cilt 18, Sayı 3, Sayfalar 611 - 623 2017-09-30

A FLUORESCENT FILM PROBE BASED ON SCHIFF BASE FOR DETERMINATION OF Fe3+ IONS

Musa KAMACI [1]

103 99

In this paper, fluorescent film probe based on Schiff base was easily prepared and it used as fluorescence chemosensor for the detection of transition metal ions in aqueous medium. Fluorescence measurements were done using fluorescence spectroscopy and the obtained results showed that the proposed sensor have two emission maxima at 539 and 582 nm. In addition, the proposed film sensor exhibited high sensitivity and selectivity to Fe3+ cation in the mentioned wavelengths. Quantum yield of the fluorescent sensor was also calculated as 3.24%. The limit of detection (LOD) of the chemosensor was calculated using fluorescence titration method and it determined as 53.7 and 3.53 µM at 539 and 582 nm. Fluorescence data indicated that the proposed sensor has potential application to determination of Fe3+ cations in deionized water without interference of the used other metal cations.


Schiff base,Chemosensor,Fe (III) ion,Fluorescent sensor
  • Hua CJ, Zheng H, Zhang K, Xin M, Gao JR, Li YJ. A novel turn off fluorescent sensor for Fe(III) and pH environment based on coumarin derivatives: the fluorescence characteristics and theoretical study. Tetrahedron 2016; 72: 8365-8372.
  • Antheraidis AN, Zachariadis GA, Stratis JA. Gallium trace on-line pre-concentration/separation and determination using a polyurethane foam mini-column and flame atomic absorption spectrometry. Application in aluminum alloys, natural waters and urine. Talanta 2003; 60: 929–936.
  • Wang Y, Liu Z, Sun J, Liu X, Pei M, Zhang G. A turn-on fluorescence probe for Fe3+ based-on benzimidazo[2,1-a] benz[de]isoquinoline-7-one derivatives. J Photoch Photobio A 2017; 332: 515–520.
  • Long Q, Wen Y, Li H, Zhang Y, Yao S. A novel fluorescent biosensor for detection of silver ions based on upconversion nanoparticles, J Fluoresc 2017; 27: 205–211.
  • Cheng X, Yu Y, Jia Y, Duan L. Fluorescent PU films for detection and removal of Hg2+, Cr3+ and Fe3+ ions. Mater Design 2016; 95: 133–140.
  • Wei J, Ren J, Liu J, Meng X, Ren X, Chen Z, Tang F. An eco-friendly, simple, and sensitive fluorescence biosensor for the detection of choline and acetylcholine based on C-dots and the Fenton reaction. Biosens Bioelectron 2014; 52: 304–309.
  • Dwivedi AK, Saikia G, Iyer PK. Aqueous polyfluorene probe for the detection and estimation of Fe3+ andinorganic phosphate in blood serum. J Mater Chem 2011; 21: 2502–2507.
  • Wu X, Xu B, Tong H, Wang L. Phosphonate-functionalized polyfluorene film sensors for sensitive detection of iron (III) in both organic and aqueous media. Macromolecules 2010; 43: 8917–8923.
  • Yang Y, Huo FJ, Yin C, Chao J, Zhang Y. An ‘OFF-ON’ fluorescent probe for specially recognize on Cys and its application in bio-imaging. Dyes Pigments 2015; 114: 105-109.
  • Saleem M, Lee KH. Selective fluorescence detection of Cu2+ in aqueous solution and living cells. J Lumin 2014; 145: 843–848.
  • Xiao W, Chen Z. Fluorescent Iron (III) Determination Based on Salicylaldehyde Functionalized Bimodal Mesoporous Silica, J Nanosci Nanotechnol 2016; 16: 12666–12670.
  • Bhamore JR, Jha S, Singhal RK, Kailasa SK. Synthesis of water dispersible fluorescent carbon nanocrystals from syzygium cumini fruits for the detection of Fe3+ ion in water and biological samples and imaging of fusarium avenaceum cells. J Fluoresc 2017; 27: 125–134
  • Wang M, Meng G, Huang Q, Qiaoling Xu Q, Guodong Liu G. A GBI@PPyNWs-based prototype of reusable fluorescence sensor for the detection of Fe3+ in aqueous solution. Anal Methods 2012; 4: 2653-2656.
  • Braun V, Hantke K. Recent insights into iron import by bacteria. Curr Opin Chem Biol 2011; 15: 328–334
  • Cao H, Chen Z, Zheng H, Huang Y. Copper nanoclusters as a highly sensitive and selective fluorescence sensor for ferric ions in serum and living cells by imaging. Biosens Bioelectron 2014; 3: 189–195.
  • Senol AM, Onganer Y, Meral K. An unusual “off-on” fluorescence sensor for iron(III) detection based on fluorescein–reduced graphene oxide functionalized with polyethylene imine. Sensor Actuat B 2017; 239: 343–351.
  • Choi YW, Park GJ, Na YJ, Jo HY, Lee SA, You GR, Kim C. A single Schiff base molecule for recognizing multiple metal ions: A fluorescence sensor for Zn(II) and Al(III) and colorimetric sensor for Fe(II) and Fe(III). Sensor Actuat B 2014; 194: 343–352.
  • Sui B, Tang S, Liu T, Kim B, Belfield KD. Novel BODIPY-based fluorescence turn-on sensor for Fe3+ and its bio-imaging application in living cells. ACS Appl Mater Interfaces 2014; 6: 18408-18412
  • Luo A, Wang H, Wang Y, Huang Q, Zhang Q. A novel colorimetric and turn-on fluorescent chemosensor for iron(III) ion detection and its application to cellular imaging. Spectrochim Acta A 2016; 168: 37-44.
  • Bhatt KD, Gupte HS, Makwana BA, Vyas DJ, Maity D, Jain VK. Calix receptor edifice; Scrupulous turn off fluorescent sensor for Fe(III), Co(II) and Cu(II). J Fluoresc 2012; 22: 1493-1500.
  • Kaya İ, Kamacı M. Synthesis, optical, electrochemical, and thermal stability properties of poly(azomethine-urethane)s. Prog Org Coat 2012; 74: 204–214.
  • Kaya İ, Kamacı M. Highly selective and stable florescent sensor for Cd(II) based on poly(azomethine-urethane). J Fluoresc 2013; 23: 115–121.
  • Kamacı M, Kaya İ. The novel poly(azomethine-urethane): Synthesis, morphological properties and application as a fluorescent probe for detection of Zn2+ ions. J Inorg Organomet Polym 2015; 25: 1250–1259.
  • Shen B, Qian Y. Click synthesis, Hg2+ sensor and intramolecular fluorescence resonance energy transfer in novel BODIPY dendrons. Sensor Actuat B 2017; 239: 226-234.
  • Sarkar D, Pramanik AK, Mondal TK. Coumarin based dual switching fluorescent ‘turn-on’ chemosensor for selective detection of Zn2+ and HSO4: An experimental and theoretical study. RSC Adv 2014; 4: 25341-25347.
  • Tian ZY, Song LN, Zhao Y, Zang FL, Zhao ZH, Chen NH, Xu XJ, Wang CJ. Spectroscopic study on the interaction between naphthalimide-polyamine conjugates and bovine serum albumin (BSA). Molecules 2015; 20: 16491-16523.
  • Kamacı M, Kaya İ. 2,4-Diamino-6-hydroxypyrimidine based poly(azomethine-urethane): synthesis and application as a fluorescent probe for detection of Cu2+ in aqueous solution. J Fluoresc 2015; 25: 1339–1349.
Konular Mühendislik ve Temel Bilimler
Dergi Bölümü Araştırma Makalesi
Yazarlar

Yazar: Musa KAMACI
E-posta: mkamaci@pirireis.edu.tr
Kurum: PIRI REIS UNIV
Ülke: Turkey


Bibtex @araştırma makalesi { aubtda292569, journal = {Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik}, issn = {1302-3160}, address = {Anadolu Üniversitesi}, year = {2017}, volume = {18}, pages = {611 - 623}, doi = {10.18038/aubtda.292569}, title = {A FLUORESCENT FILM PROBE BASED ON SCHIFF BASE FOR DETERMINATION OF Fe3+ IONS}, language = {en}, key = {cite}, author = {KAMACI, Musa} }
APA KAMACI, M . (2017). A FLUORESCENT FILM PROBE BASED ON SCHIFF BASE FOR DETERMINATION OF Fe3+ IONS. Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik, 18 (3), 611-623. Retrieved from http://dergipark.gov.tr/aubtda/issue/30003/292569
MLA KAMACI, M . "A FLUORESCENT FILM PROBE BASED ON SCHIFF BASE FOR DETERMINATION OF Fe3+ IONS". Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik 18 (2017): 611-623 <http://dergipark.gov.tr/aubtda/issue/30003/292569>
Chicago KAMACI, M . "A FLUORESCENT FILM PROBE BASED ON SCHIFF BASE FOR DETERMINATION OF Fe3+ IONS". Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik 18 (2017): 611-623
RIS TY - JOUR T1 - A FLUORESCENT FILM PROBE BASED ON SCHIFF BASE FOR DETERMINATION OF Fe3+ IONS AU - Musa KAMACI Y1 - 2017 PY - 2017 N1 - DO - T2 - Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik JF - Journal JO - JOR SP - 611 EP - 623 VL - 18 IS - 3 SN - 1302-3160-2146-0205 M3 - UR - Y2 - 2017 ER -
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