Yıl 2017, Cilt 18, Sayı 5, Sayfalar 929 - 938 2017-12-31

RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES
AKRİLOMORFOLİN İLE 2-HİDROKSİETİL METAKRİLAT'IN RADİKAL POLİMERİZASYONU: MONOMER REAKTİVİTE ORANLARI VE TERMAL ÖZELLİKLERİ

M.Mürşit Temüz [1]

181 347

                Poly (acryloylmorpholine -co- 2-hydroxyethyl methacrylate) were prepared by traditional free radical polymerization. Copolymerization with acryloylmorpholine(ACM) and 2-hydroxyethyl methacrylate(HEMA) monomers were carried out in tetrahydrofuran solution at 60oC using 2,2'-azobisisobutyronitrile(AIBN) as initiator. The copolymers were characterized by FT-IR , 1H and  13C nuclear magnetic resonance (NMR). Monomer compositions of  the copolymers were established by nitrogen results of elemental analysis. The reactivity ratios of monomers ACM(r1) and HEMA(r2) in the copolymer were calculated by various methods. According to these methods, r1 was 1.73-2.01 and  r2 was 0.48-0.74. Thermogravimetric analysis was used to investigate the thermal properties of copolymers.

                Poli (akriloilmorfolin-co-2-hidroksietil metakrilat) geleneksel serbest radikal polimerizasyonu ile hazırlandı. Akriloilmorfolin (ACM) ve 2-hidroksietil metakrilat (HEMA) monomerleriyle kopolimerizasyon, başlatıcı olarak 2,2'-azobisizobutironitril (AIBN) kullanılarak 60 ° C'de tetrahidrofuran çözeltisi içinde gerçekleştirildi. Kopolimerler, FT-IR, 1H ve 13C nükleer manyetik rezonans (NMR) ile karakterize edildi. Kopolimerlerin monomer bileşimleri, elemental analizin azot sonuçlarıyla tahmin edildi. Kopolimerdeki ACM(r1) ve HEMA(r2) monomerlerinin reaktivite oranları, çeşitli yöntemlerle hesaplandı. Bu yöntemlere göre, r1 değeri 1.73-2.01 ve r2 değeri 0.48-0.74'tür. Kopolimerlerin termal özelliklerini araştırmak için Termogravimetrik analiz kullanıldı.


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Konular Mühendislik
Dergi Bölümü Araştırma Makalesi
Yazarlar

Yazar: M.Mürşit Temüz
Ülke: Turkey


Bibtex @araştırma makalesi { aubtda306626, journal = {ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering}, issn = {1302-3160}, eissn = {2146-0205}, address = {Eskişehir Teknik Üniversitesi}, year = {2017}, volume = {18}, pages = {929 - 938}, doi = {10.18038/aubtda.306626}, title = {RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES}, key = {cite}, author = {Temüz, M.Mürşit} }
APA Temüz, M . (2017). RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES. ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering, 18 (5), 929-938. DOI: 10.18038/aubtda.306626
MLA Temüz, M . "RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 (2017): 929-938 <http://dergipark.gov.tr/aubtda/issue/31308/306626>
Chicago Temüz, M . "RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 (2017): 929-938
RIS TY - JOUR T1 - RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES AU - M.Mürşit Temüz Y1 - 2017 PY - 2017 N1 - doi: 10.18038/aubtda.306626 DO - 10.18038/aubtda.306626 T2 - ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering JF - Journal JO - JOR SP - 929 EP - 938 VL - 18 IS - 5 SN - 1302-3160-2146-0205 M3 - doi: 10.18038/aubtda.306626 UR - http://dx.doi.org/10.18038/aubtda.306626 Y2 - 2017 ER -
EndNote %0 Anadolu Üniversitesi Bilim Ve Teknoloji Dergisi A - Uygulamalı Bilimler ve Mühendislik RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES %A M.Mürşit Temüz %T RADICAL COPOLYMERIZATION OF ACRLOYLMORPHOLINE WITH 2-HYDROXYETHYL METHACRYLATE: MONOMER REACTIVITY RATIOS AND THERMAL PROPERTIES %D 2017 %J ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering %P 1302-3160-2146-0205 %V 18 %N 5 %R doi: 10.18038/aubtda.306626 %U 10.18038/aubtda.306626
ISNAD Temüz, M.Mürşit . "AKRİLOMORFOLİN İLE 2-HİDROKSİETİL METAKRİLAT'IN RADİKAL POLİMERİZASYONU: MONOMER REAKTİVİTE ORANLARI VE TERMAL ÖZELLİKLERİ". ANADOLU UNIVERSITY JOURNAL OF SCIENCE AND TECHNOLOGY A - Applied Sciences and Engineering 18 / 5 (Aralık 2017): 929-938. http://dx.doi.org/10.18038/aubtda.306626