Yıl 2018, Cilt 5, Sayı 3, Sayfalar 836 - 844 2018-09-30

Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer

Mustafa ÇAKIR [1] , Emre AKIN [2] , Perihan ULAK [3]

26 26


In this study fluorine chains were bonded with covalently in epoxy acrylate system via UV light. For this purpose, five different coating samples prepared. Bisphenol-A glycerolate diacrylate (epoxyacrylate) and 1,6-Hexanediol diacrylate were used as main coating solution. The weight ratio of Bisphenol-A glycerolate diacrylate and HDDA was calculated as 7/3. As a long fluorine chain, 1H,1H,2H,2H-perfluorodecyl acrylate (PFOA) was added into the main coating solution in the ratios of 0.25 wt  %, 0.50 wt %, 0.75 wt % and 1 wt  %. All prepared solutions were coated on aluminum plates by 75 µm by wire wound applicator and then cured via UV dryer. Physical properties of coatings were measured by test such as MEK rubbing test for solvent resistance, gloss 60o test for brightness, cross-cut test for adhesion property and pencil hardness test for scratch resistance.  Hydrophobicity was measured as static water contact angle test. The total surface energy was calculated by contact angle measurement software. In terms of mechanical properties, sheen impact test (for coating samples) and Shore - D hardness tests (for free film samples) were carried out. As a result of these tests, cross-cut adhesion and gloss 60o values decrease with the fluorine chains but favorable physical coating results were obtained. On the other hand, by the increasing within the content of the fluorine chains, Taber abrasion resistance and hydrophocity increases significantly but sheen impact resistance and Shore - D hardness values decreases slightly. In terms of cost and overall results, the most proper and multifunctional coating was seemed as 0.25 wt %.


Physical properties of epoxyacrylate, UV curable fluorine chains, Abrasion and impact resistance of coatings, Hydrophobicity
  • Referans1Chattopadhyay D.K, Panda S.S., Raju K.V.S.N., Thermal and Mechanical Properties of Epoxy Acrylate/Methacrylates UV Cured Coatings, Progress in Organic Coatings 54 (2005) 10–19
  • Referans2L. Shen, Y. Li, J. Zheng, M. Lu, K. Wu, Modified epoxy acrylate resin for photocurable temporary protective coatings, Progress in Organic Coatings 89 (2015) 17–25
  • Referans3T.C., Canak, Kaya, K., İ.E. Serhatlı, Boron Containing UV - Curable Epoxy Acrylate Coatings, Progress in Organic Coatings 77 (2014) 1911–1918
  • Referans4Y.H. Lin, K.H. Liao, C.K. Huang, N.K. Chou, S.S. Wang, S.H. Chuc, K.H. Hsieh, Superhydrophobic films of UV - Curable Fluorinated Epoxy Acrylate Resins, Polymer Int. 2010; 59: 1205–1211
  • Referans5M.K. Gosh, K.L Mittal, Polyimides: Fundamentals and Applications, Marcel Dekker, New York, 1996, pp 7–48.
  • Referans6L. Tao, H. Yang, J. Liu, L. Fan, S. Yang, Synthesis and Characterization of Highly Optical Transparent and Low Dielectric Constant Fluorinated Polyimides, Polymer 50 (2009) 6009–6018
  • Referans7K.U. Jeong, J. J. Kim, T.-H. Yoon, Synthesis and Characterization of Novel Polyimides Containing Fluorine and Phosphine Oxide Moieties, Polymer 42 (2001) 6019-6030
  • Referans8B. Jones, Technical Director, Halocarbon Products Corporation, Fluoropolymers for Coating Applications, JCT Coatings Tech Magazine 1 (2008) 1-10
  • Referans9C. Kizilkaya, S. Karataş, N.K. Apohan, A. Gungor, Synthesize and Characterization of Novel Polyimide/SiO2 Nanocomposite Materials Containing Phenyl phosphine Oxide via Sol-Gel Technique, Journal of Applied Polymer Science, 115 (2010) 3256–3264
  • Referans10M. V. Kahraman, Z. S. Akdemir, I. Kartal, N. K. Apohan, A. Gungor, Preparation of Fluorine Containing hybrid coatings: Investigation of Coating Performance onto ABS and PMMA Substrates, Polymer Adv. Technol., 22 (2011) 981–986
  • Referans11M. V. Kahraman, G. Bayramoglu, Y. Boztoprak, A. Gungor, N. K. Apohan, Synthesis of Fluorinated/Methacrylated Epoxy based Oligomers and Investigation of its Performance in the UV Curable Hybrid Coatings, Progress in Organic Coatings 66 (2009) 52–58
  • Referans12Çakir M. Investigation of Coating Performance of UV-Curable Hybrid Polymers Containing 1H,1H,2H,2H-Perfluorooctyltriethoxysilane, Coatings, (2017) 7, 37
  • Referans13Shundrina, IK, Vaganova, TA, Kusov, SZ, Rodionov, VI, Karpova, EV, Koval, VV, Gerasimova, YV, Malykhin, EV, “Synthesis and Characterization of Polyimides Based on Novel Isomeric Perfluorinated Naphthylenediamines.” Journal of Fluorine Chemistry, 130 (2009) 733–741
Birincil Dil en
Konular Mühendislik
Dergi Bölümü Makaleler
Yazarlar

Yazar: Mustafa ÇAKIR (Sorumlu Yazar)
Kurum: MARMARA ÜNİVERSİTESİ, TEKNOLOJİ FAKÜLTESİ
Ülke: Turkey


Yazar: Emre AKIN

Yazar: Perihan ULAK

Bibtex @araştırma makalesi { ecjse426693, journal = {El-Cezeri Journal of Science and Engineering}, issn = {2148-3736}, address = {Selami ŞAŞMAZ}, year = {2018}, volume = {5}, pages = {836 - 844}, doi = {10.31202/ecjse.426693}, title = {Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer}, key = {cite}, author = {ULAK, Perihan and ÇAKIR, Mustafa and AKIN, Emre} }
APA ÇAKIR, M , AKIN, E , ULAK, P . (2018). Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer. El-Cezeri Journal of Science and Engineering, 5 (3), 836-844. DOI: 10.31202/ecjse.426693
MLA ÇAKIR, M , AKIN, E , ULAK, P . "Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer". El-Cezeri Journal of Science and Engineering 5 (2018): 836-844 <http://dergipark.gov.tr/ecjse/issue/39488/426693>
Chicago ÇAKIR, M , AKIN, E , ULAK, P . "Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer". El-Cezeri Journal of Science and Engineering 5 (2018): 836-844
RIS TY - JOUR T1 - Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer AU - Mustafa ÇAKIR , Emre AKIN , Perihan ULAK Y1 - 2018 PY - 2018 N1 - doi: 10.31202/ecjse.426693 DO - 10.31202/ecjse.426693 T2 - El-Cezeri Journal of Science and Engineering JF - Journal JO - JOR SP - 836 EP - 844 VL - 5 IS - 3 SN - 2148-3736- M3 - doi: 10.31202/ecjse.426693 UR - http://dx.doi.org/10.31202/ecjse.426693 Y2 - 2018 ER -
EndNote %0 El-Cezeri Journal of Science and Engineering Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer %A Mustafa ÇAKIR , Emre AKIN , Perihan ULAK %T Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer %D 2018 %J El-Cezeri Journal of Science and Engineering %P 2148-3736- %V 5 %N 3 %R doi: 10.31202/ecjse.426693 %U 10.31202/ecjse.426693
ISNAD ÇAKIR, Mustafa , AKIN, Emre , ULAK, Perihan . "Properties of UV-Curable Bisphenol-A Glycerolate Diacrylate Coatings Containing 1H,1H,2H,2H-Perfluorodecyl Acrylate Monomer". El-Cezeri Journal of Science and Engineering 5 / 3 (Eylül 2018): 836-844. http://dx.doi.org/10.31202/ecjse.426693