Yıl 2018, Cilt , Sayı 14, Sayfalar 323 - 333 2018-12-31

Voltammetric Determination of Thiuram by Carbon Paste Electrodes Modified with Molecular Imprinted Polymers
Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini

Mert Soysal [1] , Ali Ersin Karagözler [2]

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Molecular imprinting has become a powerful tool for the preparation of three dimensional polymeric materials with special recognition ability. The three dimensionally cross-linked polymeric materials are obtained by polymerization of functional monomers in the presence of template molecule. Then, leaching of template molecules by a leaching procedure generates the recognition cavities complementary to the shape, size and functional groups of the template molecules. Thus, molecularly imprinted polymers are often used because of their stability, their resistance to temperature and pressure, resistance to effects of the chemicals and their re-use, as well as their selective properties against template molecule. Nowadays, molecular imprinting technique has been successfully assembled with a several of analytical techniques in chromatography, sensor etc.

In this study, thiuram imprinted microbeads were synthesized and characterized by Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM). A carbon paste electrode (CPE) was modified with thiuram molecular imprinted polymer (MIP) and used for the determination of thiuram in active substance of pesticide sample by Differential Pulse Voltammetry (DPV).

Spesifik tanıma özelliği bakımından molekül baskılama tekniği, üç boyutlu polimerik malzemelerin hazırlanmasında önemli bir araç haline gelmiştir. Üç boyutlu olarak çapraz bağlanmış polimerik malzemeler, kalıp molekülünün bulunduğu ortamdaki fonksiyonel monomerlerin polimerizasyonu ile elde edilirler. Daha sonra, uygun sökme prosedürüyle kalıp molekülünün şekil, boyut ve fonksiyonel gruplarına ait tamamlayıcı tanıma bölgeleri oluşturulur. Böylelikle, molekül baskılı polimerler, kalıp moleküle karşı seçici özellik göstermesinin yanı sıra kararlı bir yapıda bulunması, sıcaklığa ve basınca karşı dayanıklı, kimyasallara karşı dirençli olmaları ve tekrar kullanılabilmeleri gibi özelliklerinden dolayı sıklıkla kullanılmaktadır. Günümüzde, moleküler baskılama tekniği, kromatografi, sensör vb. gibi çeşitli analitik tekniklerle başarı bir şekilde birleştirilmiştir.

Bu çalışmada, thiuram baskılı mikroküreler sentezlendi ve FT-IR spektroskopisi ve Taramalı Elektron Mikroskobu (SEM) ile karakterize edildi. Thiuram molekülü baskılanmış polimerlerle modifiye edilmiş olan karbon pasta elektrot (CPE), difrensiyel puls voltametrisi (DPV) kullanılarak thiuram etken maddesi içeren pestisit örneğinde thiuram tayini yapılmıştır.

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Orcid: 0000-0002-5685-0261
Yazar: Mert Soysal (Sorumlu Yazar)
Kurum: ADNAN MENDERES ÜNİVERSİTESİ
Ülke: Turkey


Orcid: 0000-0001-8042-1152
Yazar: Ali Ersin Karagözler
Kurum: ADNAN MENDERES ÜNİVERSİTESİ
Ülke: Turkey


Bibtex @araştırma makalesi { ejosat476017, journal = {Avrupa Bilim ve Teknoloji Dergisi}, issn = {}, eissn = {2148-2683}, address = {Osman Sağdıç}, year = {2018}, volume = {}, pages = {323 - 333}, doi = {10.31590/ejosat.476017}, title = {Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini}, key = {cite}, author = {Soysal, Mert and Karagözler, Ali Ersin} }
APA Soysal, M , Karagözler, A . (2018). Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini. Avrupa Bilim ve Teknoloji Dergisi, (14), 323-333. DOI: 10.31590/ejosat.476017
MLA Soysal, M , Karagözler, A . "Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini". Avrupa Bilim ve Teknoloji Dergisi (2018): 323-333 <http://dergipark.gov.tr/ejosat/issue/40225/476017>
Chicago Soysal, M , Karagözler, A . "Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini". Avrupa Bilim ve Teknoloji Dergisi (2018): 323-333
RIS TY - JOUR T1 - Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini AU - Mert Soysal , Ali Ersin Karagözler Y1 - 2018 PY - 2018 N1 - doi: 10.31590/ejosat.476017 DO - 10.31590/ejosat.476017 T2 - Avrupa Bilim ve Teknoloji Dergisi JF - Journal JO - JOR SP - 323 EP - 333 VL - IS - 14 SN - -2148-2683 M3 - doi: 10.31590/ejosat.476017 UR - http://dx.doi.org/10.31590/ejosat.476017 Y2 - 2018 ER -
EndNote %0 Avrupa Bilim ve Teknoloji Dergisi Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini %A Mert Soysal , Ali Ersin Karagözler %T Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini %D 2018 %J Avrupa Bilim ve Teknoloji Dergisi %P -2148-2683 %V %N 14 %R doi: 10.31590/ejosat.476017 %U 10.31590/ejosat.476017
ISNAD Soysal, Mert , Karagözler, Ali Ersin . "Moleküler Baskılı Polimerler ile Modifiye Edilmiş Karbon Pasta Elektrotlarla Thiuramın Voltametrik Tayini". Avrupa Bilim ve Teknoloji Dergisi / 14 (Aralık 2019): 323-333. http://dx.doi.org/10.31590/ejosat.476017