Year 2019, Volume , Issue 15, Pages 1 - 9 2019-03-31

Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application
Enerji Uygulamasında Co katkılı MOF-5/Poliimit Karışık Matriksli Membranlar Kullanarak Hidrojen Ayrımı

Hülya Aykaç Özen [1] , Bahtiyar Öztürk [2]

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Hydrogen is the most abundant element in the universe, can be produced by water, stored easily, conversed into thermal, mechanical and electrical energy so it can be considered as the energy carrier of the future due to these characteristics . Hydrogen separation using membrane method has the advantage over other separation methods in that it is less energy intensive and environmental friendly. In order to membrane properties become better and increase the performance of gas separation membranes, mixed matrix membranes (MMMs) have been developed. MOFs as a new fillers in MMM with high surface area and pore volume enhance the H2 gas separation properties. In this study, MOF-5 and Co-doped MOF-5 particles were synthesized, characterized and incorporated into polyimide to investigate the effect of filler on the H2 gas permeation. Co-doped MOF-5/PI MMMs with different loading rate (5wt.%, 10wt.%, 15wt.%) were fabricated. The characterization was performed by different analysis techniques. The gas analyses results showed that permeability of H2 gas in mixed matrix membrane including MOF-5 and Co-doped MOF-5 particules, enhanced with increasing the loading rate (5wt.%, 10wt.%, 15wt.%) at room temperature and pressure of 500 kPa. Furthermore, metal doped  MOFs/PI is the highest gas permeation properties compared to pure PI and MOF-5/PI.

Evrende bol miktarda bulunan hidrojen, su tarafından üretilebilir, kolayca depolanabilir, termal, mekanik ve elektrik enerjisine dönüşebilir, bu özelliklerinden dolayı geleceğin enerji taşıyıcısı olarak düşünülebilir. Membran metodu kullanılarak hidrojen ayırma, diğer ayırma yöntemlerine göre daha az enerji yoğunluğu ve çevre dostu olması gibi olumlu yönlere sahiptir. Gaz ayırma membranlarının performansının arttırılması ve membran özelliklerinin daha iyi hale gelmesi için karışık matris membranlar (MMM'ler) geliştirilmiştir. Karışık matriksli membranlarda dolgu maddesi olarak kullanılabilen, yüksek yüzey alanı ve gözenek hacmine sahip MOF'lar, H2 gazı ayırma özelliklerini arttırmaktadır. Bu çalışmada, MOF-5 ve Co katkılı MOF-5 partikülleri sentezlenmiş, karakterize edilmiş ve dolgu maddesinin H2 gaz geçirgenliği üzerindeki etkisini araştırmak için poliimid içine katılmıştır. Farklı yükleme oranlarına sahip katkılı MOF-5/PI MMM'ler (ağırlıkça % 5, % 10 ve % 15) üretilmiştir ve karakterizasyonları farklı analiz teknikleriyle gerçekleştirilmiştir. Gaz analiz sonuçları, MOF-5 ve Co katkılı MOF-5 dahil olmak üzere karışık matriksli membranda H2 gazının geçirgenliğinin, oda sıcaklığında ve 500 kPa'lık basınç altında farklı yükleme oranlarında (ağırlıkça% 5,% 10,% 15) arttığını göstermiştir. Ayrıca, metal katkılı MOF/PI’in, saf PI ve MOF-5/PI ile karşılaştırıldığında en yüksek gaz geçirgenlik özelliklerine sahip olduğu görülmüştür.
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Primary Language en
Subjects Engineering
Journal Section Makaleler
Authors

Orcid: 0000-0001-2345-6789
Author: Hülya Aykaç Özen (Primary Author)
Country: Turkey


Orcid: 0000-0002-3385-0701
Author: Bahtiyar Öztürk

Bibtex @research article { ejosat456464, journal = {Avrupa Bilim ve Teknoloji Dergisi}, issn = {}, eissn = {2148-2683}, address = {Osman Sağdıç}, year = {2019}, volume = {}, pages = {1 - 9}, doi = {10.31590/ejosat.456464}, title = {Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application}, key = {cite}, author = {Aykaç Özen, Hülya and Öztürk, Bahtiyar} }
APA Aykaç Özen, H , Öztürk, B . (2019). Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application. Avrupa Bilim ve Teknoloji Dergisi, (15), 1-9. DOI: 10.31590/ejosat.456464
MLA Aykaç Özen, H , Öztürk, B . "Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application". Avrupa Bilim ve Teknoloji Dergisi (2019): 1-9 <http://dergipark.gov.tr/ejosat/issue/43603/456464>
Chicago Aykaç Özen, H , Öztürk, B . "Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application". Avrupa Bilim ve Teknoloji Dergisi (2019): 1-9
RIS TY - JOUR T1 - Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application AU - Hülya Aykaç Özen , Bahtiyar Öztürk Y1 - 2019 PY - 2019 N1 - doi: 10.31590/ejosat.456464 DO - 10.31590/ejosat.456464 T2 - Avrupa Bilim ve Teknoloji Dergisi JF - Journal JO - JOR SP - 1 EP - 9 VL - IS - 15 SN - -2148-2683 M3 - doi: 10.31590/ejosat.456464 UR - https://doi.org/10.31590/ejosat.456464 Y2 - 2019 ER -
EndNote %0 European Journal of Science and Technology Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application %A Hülya Aykaç Özen , Bahtiyar Öztürk %T Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application %D 2019 %J Avrupa Bilim ve Teknoloji Dergisi %P -2148-2683 %V %N 15 %R doi: 10.31590/ejosat.456464 %U 10.31590/ejosat.456464
ISNAD Aykaç Özen, Hülya , Öztürk, Bahtiyar . "Hydrogen Separation using Co-doped MOF-5/Polyimide Mixed Matrix Membrane for Energy Application". Avrupa Bilim ve Teknoloji Dergisi / 15 (March 2019): 1-9. https://doi.org/10.31590/ejosat.456464