Cilt 20, Sayı 3, Sayfalar 159 - 164 2017-09-01

(Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil

Pollyana M. S. Kalvelage [1] , Allan A. Albuquerque [2] , António A. C. Barros [3] , Sávio L. Bertoli [4]

35 40

In order to provide new isobaric vapor−liquid equilibrium (VLE) data for ethanol-biodiesel systems, experimental boiling points for mixtures of ethanol + biodiesel from soybean oil (SB) and frying oil (FB) were measured. UNIFAC and NRTL models were used to predict and correlate the data, in order to better represent the VLE in process simulation. VLE data were measured with a Fischer type ebulliometer. Reliability and reproducibility were evaluated with VLE data for ethanol + water system at 101.32 kPa. These data also proved to be thermodynamically consistent based on the area test. The boiling temperatures for ethanol + biodiesel systems agreed with other results reported at same pressure for SB and for biodiesel from sunflower seed oil (SSB). The thermodynamic modelling using the NRTL model obtained lower AAD values than those from UNIFAC, assuring better safety in the design and simulations steps of a biodiesel production plant.

Biodiesel; Ethanol; NRTL; UNIFAC; Vapor−liquid equilibrium
  • [1] M. Balat, H. Balat, "A critical review of bio-diesel as a vehicular fuel," Energy Conversion and Management, 49, 2727-2741, 2008. [2] A. Gnanaprakasam, V. M. Sivakumar, A. Surendhar, M. Thirumarimurugan, T. Kannadasan, "Recent strategy of biodiesel production from waste cooking oil and process influencing parameters: a review," Journal of Energy, 2013, 2013. [3] A. A. Albuquerque, L. Danielski, L. Stragevitch, "Techno-economic assessment of an alternative process for biodiesel production from feedstock containing high levels of free fatty acids," Energy & Fuels, 30, 9409–9418, 2016. [4] Y. Zhang, M. Dube, D. McLean, M. Kates, "Biodiesel production from waste cooking oil: 1. Process design and technological assessment," Bioresource Technology, 89, 1-16, 2003. [5] A. Amelio, L. Loise, R. Azhandeh, S. Darvishmanesh, V. Calabró, J. Degrève, P. Luis, B. Van der Bruggen, "Purification of biodiesel using a membrane contactor: Liquid–liquid extraction," Fuel Processing Technology, 142, 352-360, 2016. [6] R. Coelho, P. G. Dos Santos, M. R. Mafra, L. Cardozo-Filho, M. L. Corazza, "(Vapor+ liquid) equilibrium for the binary systems {water+ glycerol} and {ethanol+ glycerol, ethyl stearate, and ethyl palmitate} at low pressures," The Journal of Chemical Thermodynamics, 43, 1870-1876, 2011. [7] A. F. Young, F. L. Pessoa, E. M. Queiroz, "Comparison between Biodiesel Production from Soybean Oil and Palm Oil with Ethanol: Design and Economic Evaluation," Chem. Eng. Trans., 43, 325-330, 2015. [8] L. A. Follegatti-Romero, M. B. Oliveira, F. R. Batista, E. A. Batista, J. A. Coutinho, A. J. Meirelles, "Liquid–liquid equilibria for ternary systems containing ethyl esters, ethanol and glycerol at 323.15 and 353.15 K," Fuel, 94, 386-394, 2012. [9] L. Meher, D. V. Sagar, S. Naik, "Technical aspects of biodiesel production by transesterification—a review," Renewable and Sustainable Energy Reviews, 10, 248-268, 2006. [10] J. Marchetti, V. Miguel, A. Errazu, "Possible methods for biodiesel production," Renewable and Sustainable Energy Reviews, 11, 1300-1311, 2007. [11] D. I. S. Silva, M. R. Mafra, F. R. Silva, P. M. Ndiaye, L. P. Ramos, L. Cardozo Filho, M. L. Corazza, "Liquid–liquid and vapor–liquid equilibrium data for biodiesel reaction–separation systems," Fuel, 108, 269-276, 2013. [12] F. Ma, M. A. Hanna, "Biodiesel production: a review," Bioresource Technology, 70, 1-15, 1999. [13] J. Žaglinskis, K. Lukács, Á. Bereczky, "Comparison of properties of a compression ignition engine operating on diesel–biodiesel blend with methanol additive," Fuel, 2016. [14] M. Archer, A. Szklo, "Can increasing gasoline supply in the United States affect ethanol production in Brazil?," Renewable Energy, 95, 586-596, 2016. [15] Y. Guo, J. Zhong, Y. Xing, D. Li, R. Lin, "Volatility of blended fuel of biodiesel and ethanol," Energy & Fuels, 21, 1188-1192, 2007. [16] A. Fredenslund, R. L. Jones, J. M. Prausnitz, "Group–contribution estimation of activity coefficients in nonideal liquid mixtures," AIChE Journal, 21, 1086-1099, 1975. [17] H. Renon, J. M. Prausnitz, "Local compositions in thermodynamic excess functions for liquid mixtures," AIChE Journal, 14, 135-144, 1968. [18] K. Colombo, L. Ender, A. A. C. Barros, "The study of biodiesel production using CaO as a heterogeneous catalytic reaction," Egypt. J. Petrol, In Press, 2016. DOI: https://doi.org/10.1016/j.ejpe.2016.05.006 [19]T. M. Peruzzolo, V. R. Wiggers, H. F. Meier, E. L. Simionatto, D. R. Scharf, L. Ender, "Biodiesel production by homogeneous transesterification via reactive distillation column," Blucher Chemical Engineering Proceedings, 1, 1567-11573, 2014. DOI: 10.5151/chemeng-cobeq2014-0574-24881-165851 [20] F. Labor-UND, Manual of operation of the apparatus Fischer 10, 602. 1997. [21] C. S. M. Gomes, H. N. M. de Oliveira, O. Chiavone-Filho, E. L. Foletto, "Vapor–liquid equilibria for ethyl acetate + methanol and ethyl acetate + ethanol mixtures: Experimental verification and prediction," Chemical Engineering Research and Design, 92, 2861-2866, 2014. [22] J. M. Smith, H. C. Van Ness, M. M. Abbott, Introduction to chemical engineering thermodynamics. 7 ed. McGraw-Hill, 2005. [23] L. Stragevitch, S. d’Avila, "Application of a generalized maximum likelihood method in the reduction of multicomponent liquid-liquid equilibrium data," Brazilian Journal of Chemical Engineering, 14, 1997. DOI: 10.1590/S0104-66321997000100004 [24] E. Herington, "A thermodynamic test for the internal consistency of experimental data on volatility ratios," Nature, 160, 610-611, 1947. [25] O. Redlich, A. Kister, "Algebraic representation of thermodynamic properties and the classification of solutions," Industrial & Engineering Chemistry, 40, 345-348, 1948. [26] K. Iwakabe, H. Kosuge, "Isobaric vapor–liquid–liquid equilibria with a newly developed still," Fluid Phase Equilibria, 192, 171-186, 2001. [27] R. Ceriani, R. Gani, Y. Liu, "Prediction of vapor pressure and heats of vaporization of edible oil/fat compounds by group contribution," Fluid Phase Equilibria, 337, 53-59, 2013. [28] R. Alcantara, J. Amores, L. t. Canoira, E. Fidalgo, M. Franco, A. Navarro, "Catalytic production of biodiesel from soy-bean oil, used frying oil and tallow," Biomass and Bioenergy, 18, 515-527, 2000. [29] C. W. Bonhorst, P. M. Althouse, H. O. Triebold, "Esters of naturally occurring fatty acids-physical properties of methyl, propyl, and isopropyl esters of C6 to C18 saturated fatty acids," Industrial & Engineering Chemistry, 40, 2379-2384, 1948. [30] T. A. Scott, D. Macmillan, E. H. Melvin, "Vapor pressures and distillation of methyl esters of some fatty acids," Industrial & Engineering Chemistry, 44, 172-175, 1952. [31] A. Rose, W. R. Supina, "Vapor Pressure and Vapor-Liquid Equilibrium Data for Methyl Esters of the Common Saturated Normal Fatty Acids," Journal of Chemical and Engineering Data, 6, 173-179, 1961. [32] A. Rose, V. N. Schrodt, "Vapor-Liquid Equilibria for the Methyl Oleate and Methyl Stearate Binary System," Journal of Chemical & Engineering Data, 9, 12-16, 1964. [33] L. Y. A. Silva, R. M. M. Falleiro, A. J. A. Meirelles, M. A. Kraehenbuehl, "Determination of the vapor pressure of ethyl esters by Differential Scanning Calorimetry," The Journal of Chemical Thermodynamics, 43, 943-947, 2011. [34] ABNT, INMETRO, Guide to the Expression of Uncertainty in Measurement (in portuguese). 3 ed. Brazil: SERIFA Comunicação, 2003.
Konular
Dergi Bölümü Regular Original Research Article
Yazarlar

Yazar: Pollyana M. S. Kalvelage
E-posta: allan.almeida@ufpe.br

Yazar: Allan A. Albuquerque
E-posta: allan.almeida@ufpe.br

Yazar: António A. C. Barros
E-posta: allan.almeida@ufpe.br

Yazar: Sávio L. Bertoli
E-posta: allan.almeida@ufpe.br

Bibtex @araştırma makalesi { eoguijt337160, journal = {International Journal of Thermodynamics}, issn = {1301-9724}, address = {Yaşar DEMİREL}, year = {2017}, volume = {20}, pages = {159 - 164}, doi = {}, title = {(Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil}, language = {en}, key = {cite}, author = {Bertoli, Sávio L. and Kalvelage, Pollyana M. S. and Barros, António A. C. and Albuquerque, Allan A.} }
APA Kalvelage, P , Albuquerque, A , Barros, A , Bertoli, S . (2017). (Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil. International Journal of Thermodynamics, 20 (3), 159-164. Retrieved from http://dergipark.gov.tr/eoguijt/issue/31047/337160
MLA Kalvelage, P , Albuquerque, A , Barros, A , Bertoli, S . "(Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil". International Journal of Thermodynamics 20 (2017): 159-164 <http://dergipark.gov.tr/eoguijt/issue/31047/337160>
Chicago Kalvelage, P , Albuquerque, A , Barros, A , Bertoli, S . "(Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil". International Journal of Thermodynamics 20 (2017): 159-164
RIS TY - JOUR T1 - (Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil AU - Pollyana M. S. Kalvelage , Allan A. Albuquerque , António A. C. Barros , Sávio L. Bertoli Y1 - 2017 PY - 2017 N1 - DO - T2 - International Journal of Thermodynamics JF - Journal JO - JOR SP - 159 EP - 164 VL - 20 IS - 3 SN - 1301-9724-2146-1511 M3 - UR - Y2 - 2017 ER -
EndNote %0 International Journal of Thermodynamics (Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil %A Pollyana M. S. Kalvelage , Allan A. Albuquerque , António A. C. Barros , Sávio L. Bertoli %T (Vapor + Liquid) Equilibrium for Mixtures Ethanol + Biodiesel from Soybean Oil and Frying Oil %D 2017 %J International Journal of Thermodynamics %P 1301-9724-2146-1511 %V 20 %N 3 %R %U