Yıl 2018, Cilt 21, Sayı 3, Sayfalar 136 - 142 2018-09-01

Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study

S. E. Olaseni [1] , O. A. Akeremale [2] , M. O. Osundiya [3] , C. O. Aboluwoye [4] , A. Orunesajo [5] , O. E. Oyeneyin [6] , E. O. Oniya [7]

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Simple and differential Uv/Visible spectroscopic method were used to monitored the interaction of Sodium dodecyl sulphate (SDS) and Sodium – N- laouryl sarcosinate (SLS) with crystal violet (CV) in pre-micellar and post-micellar concentration range. The results showed that the peak of CV at 590nm was unperturbed in CV/SDS system, but the intensity increased as surfactant concentration increased, unlike in the CV/SLS system. This is an indication that strong interaction occurred between CV and surfactants molecule. Absorption data were also used to obtain partition coefficient () values and binding constant () values from which the free energy of partition () and the free energy of binding () were estimated. From the partition coefficient () values, it could be inferred that the solubilization of CV is more pronounced and spontaneous in the SDS than in the SLS micellar media.

Partitioning coefficient, surfactant, sarcosinate, binding constant
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Yazarlar

Yazar: S. E. Olaseni (Sorumlu Yazar)
Kurum: Department of Chemistry and Industrial Chemistry, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.
Ülke: Nigeria


Yazar: O. A. Akeremale
Kurum: Department of Chemistry and Industrial Chemistry, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.
Ülke: Nigeria


Yazar: M. O. Osundiya
Kurum: Lagos State University, Apapa, Lagos, Nijerya
Ülke: Nigeria


Yazar: C. O. Aboluwoye
Kurum: Department of Chemistry and Industrial Chemistry, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.
Ülke: Nigeria


Yazar: A. Orunesajo
Kurum: Department of Chemistry and Industrial Chemistry, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.
Ülke: Nigeria


Yazar: O. E. Oyeneyin
Kurum: Department of Chemistry and Industrial Chemistry, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.
Ülke: Nigeria


Yazar: E. O. Oniya
Kurum: Department of Chemistry and Industrial Chemistry, Adekunle Ajasin University, Akungba-Akoko, Ondo State, Nigeria.
Ülke: Nigeria


Bibtex @araştırma makalesi { ijot414585, journal = {International Journal of Thermodynamics}, issn = {1301-9724}, eissn = {2146-1511}, address = {Yaşar DEMİREL}, year = {2018}, volume = {21}, pages = {136 - 142}, doi = {10.5541/ijot.414585}, title = {Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study}, key = {cite}, author = {Olaseni, S. E. and Oyeneyin, O. E. and Akeremale, O. A. and Osundiya, M. O. and Oniya, E. O. and Aboluwoye, C. O. and Orunesajo, A.} }
APA Olaseni, S , Akeremale, O , Osundiya, M , Aboluwoye, C , Orunesajo, A , Oyeneyin, O , Oniya, E . (2018). Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study. International Journal of Thermodynamics, 21 (3), 136-142. DOI: 10.5541/ijot.414585
MLA Olaseni, S , Akeremale, O , Osundiya, M , Aboluwoye, C , Orunesajo, A , Oyeneyin, O , Oniya, E . "Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study". International Journal of Thermodynamics 21 (2018): 136-142 <http://dergipark.gov.tr/ijot/issue/38992/414585>
Chicago Olaseni, S , Akeremale, O , Osundiya, M , Aboluwoye, C , Orunesajo, A , Oyeneyin, O , Oniya, E . "Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study". International Journal of Thermodynamics 21 (2018): 136-142
RIS TY - JOUR T1 - Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study AU - S. E. Olaseni , O. A. Akeremale , M. O. Osundiya , C. O. Aboluwoye , A. Orunesajo , O. E. Oyeneyin , E. O. Oniya Y1 - 2018 PY - 2018 N1 - doi: 10.5541/ijot.414585 DO - 10.5541/ijot.414585 T2 - International Journal of Thermodynamics JF - Journal JO - JOR SP - 136 EP - 142 VL - 21 IS - 3 SN - 1301-9724-2146-1511 M3 - doi: 10.5541/ijot.414585 UR - http://dx.doi.org/10.5541/ijot.414585 Y2 - 2018 ER -
EndNote %0 International Journal of Thermodynamics Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study %A S. E. Olaseni , O. A. Akeremale , M. O. Osundiya , C. O. Aboluwoye , A. Orunesajo , O. E. Oyeneyin , E. O. Oniya %T Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study %D 2018 %J International Journal of Thermodynamics %P 1301-9724-2146-1511 %V 21 %N 3 %R doi: 10.5541/ijot.414585 %U 10.5541/ijot.414585
ISNAD Olaseni, S. E. , Akeremale, O. A. , Osundiya, M. O. , Aboluwoye, C. O. , Orunesajo, A. , Oyeneyin, O. E. , Oniya, E. O. . "Crystal Violet Partitioning in Anionic Surfactants Micellar Media: UV-Visible Spectroscopy Study". International Journal of Thermodynamics 21 / 3 (Eylül 2018): 136-142. http://dx.doi.org/10.5541/ijot.414585