Yıl 2015, Cilt 2, Sayı 4, Sayfalar 32 - 41 2015-05-07

Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups
Aromatik azo grupları ile modifiye edilmiş, yakın-IR bölgede soğurma yapan metalsiz ve çinko(II) ftalosiyaninlerin sentezi ve karakterizasyonu

Mukaddes Özçeşmeci [1]

396 246

Metal-free and zinc(II) phthalocyanine complexes bearing peripheral (E)-4-((2-hydroxynaphthalen-1-yl)diazenyl) units have been synthesized. Novel phthalonitrile derivative required for the preparation of phthalocyanine complexes was prepared by coupling 4-aminophthalonitrile and 2-naphthol. The structures of these new compounds were characterized by using elemental analyses, proton nuclear magnetic resonance, fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, fluorescence spectroscopy and mass spectrometry. In the UV-Vis spectra a broad absorption band appears for phthalocyanine complexes at around 450–500 nm resulting from azo-group introduced onto the phthalocyanine ring. The photophysical properties of metal-free and zinc(II) phthalocyanines were studied in tetrahydrofuran.

Metal-free and zinc(II) phthalocyanine complexes bearing peripheral (E)-4-((2-hydroxynaphthalen-1-yl)diazenyl) units have been synthesized. Novel phthalonitrile derivative required for the preparation of phthalocyanine complexes was prepared by coupling 4-aminophthalonitrile and 2-naphthol. The structures of these new compounds were characterized by using elemental analyses, proton nuclear magnetic resonance, fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, fluorescence spectroscopy and mass spectrometry. In the UV-Vis spectra a broad absorption band appears for phthalocyanine complexes at around 450–500 nm resulting from azo-group introduced onto the phthalocyanine ring. The photophysical properties of metal-free and zinc(II) phthalocyanines were studied in tetrahydrofuran.

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Yazar: Mukaddes Özçeşmeci

Bibtex @ { jotcsa201859, journal = {Journal of the Turkish Chemical Society, Section A: Chemistry}, issn = {}, eissn = {2149-0120}, address = {Türkiye Kimya Derneği}, year = {2015}, volume = {2}, pages = {32 - 41}, doi = {10.18596/jotcsa.23804}, title = {Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups}, key = {cite}, author = {Özçeşmeci, Mukaddes} }
APA Özçeşmeci, M . (2015). Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups. Journal of the Turkish Chemical Society, Section A: Chemistry, 2 (4), 32-41. Retrieved from http://dergipark.gov.tr/jotcsa/issue/19067/201859?publisher=turchemsoc
MLA Özçeşmeci, M . "Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups". Journal of the Turkish Chemical Society, Section A: Chemistry 2 (2015): 32-41 <http://dergipark.gov.tr/jotcsa/issue/19067/201859?publisher=turchemsoc>
Chicago Özçeşmeci, M . "Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups". Journal of the Turkish Chemical Society, Section A: Chemistry 2 (2015): 32-41
RIS TY - JOUR T1 - Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups AU - Mukaddes Özçeşmeci Y1 - 2015 PY - 2015 N1 - DO - T2 - Journal of the Turkish Chemical Society, Section A: Chemistry JF - Journal JO - JOR SP - 32 EP - 41 VL - 2 IS - 4 SN - -2149-0120 M3 - UR - Y2 - 2019 ER -
EndNote %0 Journal of the Turkish Chemical Society, Section A: Chemistry Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups %A Mukaddes Özçeşmeci %T Synthesis and characterization of near-IR absorbing metal-free and zinc(II) phthalocyanines modified with aromatic azo groups %D 2015 %J Journal of the Turkish Chemical Society, Section A: Chemistry %P -2149-0120 %V 2 %N 4 %R %U
ISNAD Özçeşmeci, Mukaddes . "Aromatik azo grupları ile modifiye edilmiş, yakın-IR bölgede soğurma yapan metalsiz ve çinko(II) ftalosiyaninlerin sentezi ve karakterizasyonu". Journal of the Turkish Chemical Society, Section A: Chemistry 2 / 4 (Mayıs 2015): 32-41.


Novel phthalocyanines containing azo chromophores; synthesis, characterization, photophysical, and electrochemical properties
Journal of Porphyrins and Phthalocyanines
Ebru Özkan Garip
DOI: 10.1142/S1088424618500050