Yıl 2018, Cilt 22, Sayı 1, Sayfalar 237 - 246 2017-06-17

Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması

Ayça DEMİREL ÖZEL [1] , Semra MURATOĞLU [2] , H. Elif KORMALI ERTÜRÜN [3]

919 294

Dibromo[1,1′-bis(difenilfosfin)ferrosen] paladyum(II) (iyonofor I) ve dikloro[1,1′-bis(difenilfosfin)ferrosen] paladyum(II) (iyonofor II) olarak adlandırılan paladyum komplekslerinin kullanıldığı yeni iyodür-seçici karbon pasta elektrotlar hazırlandı. İyonofor I ve II kullanılarak optimum karbon pasta bileşimiyle hazırlanan elektrotların pH 4,0’da sırasıyla −43,2 ± 0,6 mV/pI ve −43,8 ± 0,6 mV/pI eğimle, 3,5×10−6 M ve 3,7×10−7 M gözlenebilme sınırıyla, 1,0×10−5 − 1,0×10−1 M ve 1,0×10−6 − 1,0×10−1 M derişim aralığında doğrusal cevap verdikleri gözlendi. Önerilen elektrotların kısa cevap sürelerine, 3 aylık ömre, iyi bir tekrarlanabilirlik ve üretilebilirliğe sahip oldukları bulundu. Ayrıca, elektrotlar, iyodür içeren ilaç numunelerinde iyodürün potansiyometrik tayini için indikatör elektrot olarak başarılı bir şekilde kullanıldı.
Karbon pasta elektrot, İyodür-seçici elektrot; Potansiyometri; Paladyum kompleksleri
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Konular
Dergi Bölümü Makaleler
Yazarlar

Yazar: Ayça DEMİREL ÖZEL
E-posta: ademirel@science.ankara.edu.tr

Yazar: Semra MURATOĞLU
E-posta: smuratoglu@ankara.edu.tr

Yazar: H. Elif KORMALI ERTÜRÜN
E-posta: kormali@science.ankara.edu.tr

Bibtex @ { sdufenbed425703, journal = {Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi}, issn = {}, address = {Süleyman Demirel Üniversitesi}, year = {2017}, volume = {22}, pages = {237 - 246}, doi = {10.19113/sdufbed.82321}, title = {Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması}, key = {cite}, author = {MURATOĞLU, Semra and KORMALI ERTÜRÜN, H. Elif and DEMİREL ÖZEL, Ayça} }
APA DEMİREL ÖZEL, A , MURATOĞLU, S , KORMALI ERTÜRÜN, H . (2017). Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 22 (1), 237-246. Retrieved from http://dergipark.gov.tr/sdufenbed/issue/37055/425703
MLA DEMİREL ÖZEL, A , MURATOĞLU, S , KORMALI ERTÜRÜN, H . "Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması". Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 (2017): 237-246 <http://dergipark.gov.tr/sdufenbed/issue/37055/425703>
Chicago DEMİREL ÖZEL, A , MURATOĞLU, S , KORMALI ERTÜRÜN, H . "Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması". Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 22 (2017): 237-246
RIS TY - JOUR T1 - Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması AU - Ayça DEMİREL ÖZEL , Semra MURATOĞLU , H. Elif KORMALI ERTÜRÜN Y1 - 2017 PY - 2017 N1 - DO - T2 - Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi JF - Journal JO - JOR SP - 237 EP - 246 VL - 22 IS - 1 SN - -1308-6529 M3 - UR - Y2 - 2018 ER -
EndNote %0 Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması %A Ayça DEMİREL ÖZEL , Semra MURATOĞLU , H. Elif KORMALI ERTÜRÜN %T Paladyum Komplekslerine Dayalı İyodür-Seçici Karbon Pasta Elektrot Hazırlanması %D 2017 %J Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi %P -1308-6529 %V 22 %N 1 %R %U