Cilt 18, Sayı 1, Sayfalar 1 - 7 2017-03-10

SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI
SYNTHESIS AND ANTIMICROBIAL ACTIVITY OF IRON CYCLOHEXANEDICARBOXYLIC ACID AND EXAMINATION OF pH EFFECT ON EXTRACTION IN WATER AND ORGANIC PHASES

Nilgün Becenen [1] , Gühergül ULUÇAM [2] , Özlen ALTUN [3]

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Bu çalışmada, reflux şartlarında demir siklohekzandikarboksilli asit sentezlenmiştir. Kompleksin yapısı fizikokimyasal ve spektroskopik metodlarla karakterize edilmiştir. Daha sonra reaksiyon sırasında pH’ın su ve organik fazlardaki paylaşma sabitleri () ve ekstraksiyon yüzdelerine (%E) etkisi ekstraksiyon metodu ile incelenmiştir. Deney sonucunda, su fazındaki Fe2+ iyonlarının çoğu pH=7.5’ta organik faza geçmiştir. Bu pH’tan sonra ekstraksiyon yüzdesi su fazından organik faza geçiş yüzünden azalmıştır. Demir siklohekzandikarboksilli asit eter, petrol eteri, benzol ve karbon tetra klorür ile sulu çözeltilerinden ekstre edilmiş, ilave olarak kompleksin mikrobiyal aktiviteleri çalışılmıştır. Aktivite sonuçları, demir siklohekzandikarboksilli asitin önemli antibakteriyal ve antifungal aktiviteye sahip olduğunu göstermiştir.

In this study, iron cyclohexanedicarboxylic acid was synthesized under refluxing conditions. The structural characterization of the complex was performed by using physico-chemical and spectroscopic methods. The effect of pH on division constant (µ) and extraction percentages (% E) in water and organic phase was investigated with the extraction method. At the end of the experiment, most of the Fe2+ ions in the water phase at pH=7.5 passed into the organic phase. Above this pH, the extraction percentage decreased because of the transition from water phase to organic phase. Iron cyclohexanedicarboxylic acid was extracted with ether, petroleum ether, benzole and carbon tetrachloride from aqueous solution and microbial activities of the complex were studied. The activity data showed that iron cyclohexanedicarboxylic acid has an important antibacterial and antifungal activities.

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Konular Yaşam Bilimleri
Dergi Bölümü Araştırma Makalesi/Research Article
Yazarlar

Yazar: Nilgün Becenen
E-posta: ozlenaltun@yahoo.com
Ülke: Turkey


Yazar: Gühergül ULUÇAM
E-posta: gulergul@trakya.edu.tr

Yazar: Özlen ALTUN
E-posta: ozlenaltun@yahoo.com
Ülke: Turkey


Bibtex @araştırma makalesi { trkjnat284521, journal = {Trakya University Journal of Natural Sciences}, issn = {2147-0294}, address = {Trakya Üniversitesi}, year = {2017}, volume = {18}, pages = {1 - 7}, doi = {10.23902/trkjnat.284521}, title = {SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI}, language = {tr}, key = {cite}, author = {ALTUN, Özlen and Becenen, Nilgün and ULUÇAM, Gühergül} } @araştırma makalesi { trkjnat284521, journal = {Trakya University Journal of Natural Sciences}, issn = {2147-0294}, address = {Trakya Üniversitesi}, year = {2017}, volume = {18}, pages = {1 - 7}, doi = {10.23902/trkjnat.284521}, title = {SYNTHESIS AND ANTIMICROBIAL ACTIVITY OF IRON CYCLOHEXANEDICARBOXYLIC ACID AND EXAMINATION OF pH EFFECT ON EXTRACTION IN WATER AND ORGANIC PHASES}, language = {en}, key = {cite}, author = {ALTUN, Özlen and Becenen, Nilgün and ULUÇAM, Gühergül} }
APA Becenen, N , ULUÇAM, G , ALTUN, Ö . (2017). SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI. Trakya University Journal of Natural Sciences, 18 (1), 1-7. DOI: 10.23902/trkjnat.284521
MLA Becenen, N , ULUÇAM, G , ALTUN, Ö . "SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI". Trakya University Journal of Natural Sciences 18 (2017): 1-7 <http://dergipark.gov.tr/trkjnat/issue/30632/284521>
Chicago Becenen, N , ULUÇAM, G , ALTUN, Ö . "SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI". Trakya University Journal of Natural Sciences 18 (2017): 1-7
RIS TY - JOUR T1 - SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI AU - Nilgün Becenen , Gühergül ULUÇAM , Özlen ALTUN Y1 - 2017 PY - 2017 N1 - doi: 10.23902/trkjnat.284521 DO - 10.23902/trkjnat.284521 T2 - Trakya University Journal of Natural Sciences JF - Journal JO - JOR SP - 1 EP - 7 VL - 18 IS - 1 SN - 2147-0294-2528-9691 M3 - doi: 10.23902/trkjnat.284521 UR - http://dx.doi.org/10.23902/trkjnat.284521 Y2 - 2017 ER -
EndNote %0 Trakya University Journal of Natural Sciences SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI %A Nilgün Becenen , Gühergül ULUÇAM , Özlen ALTUN %T SIKLOHEKZANDIKARBOKSILLI ASIDIN SENTEZI VE pH ETKISI İLE SU VE ORGANIK FAZLARDAN EKSTRAKSIYONUNUN İNCELENMESI %D 2017 %J Trakya University Journal of Natural Sciences %P 2147-0294-2528-9691 %V 18 %N 1 %R doi: 10.23902/trkjnat.284521 %U 10.23902/trkjnat.284521